Rossi will play for the third La Liga side after stints at Villarreal from 2007 to 2013 and Levante last season, reports Efe.
During his time at Villarreal, he scored 80 goals in 181 games, and scored six goals in 17 games for Levante last season.
Rossi will be officially presented on Tuesday at Balaidos stadium. The Italian striker is the fifth signing for the Spanish team, coached by Eduardo 'Toto' Berizzo.
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