Naresh Pal, who was posted with the Special Branch of Delhi Police, was hit from behind near Seelampur area in east Delhi around 8.15 a.m.
Pal was rushed to Guru Teg Bahadur hospital where doctors pronounced him dead, a police officer said.
He said car driver Shubham was arrested from the spot and booked under section 304 A (causing death by negligence).
The officer added that Pal had joined Delhi Police in 1982 and was residing with his family in Surya Nagar in Uttar Pradesh's Ghaziabad district.
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